Hola amigos he encontrado esta validacion de email, espero les sirva
Function ChkValidEmail(ByVal Value As String, Optional ByVal MaxLength As _
Integer = 255, Optional ByVal IsRequired As Boolean = True) As Boolean
If Value Is Nothing OrElse Value.Length = 0 Then
' rule out the null string case
Return Not IsRequired
ElseIf Value.Length > MaxLength Then
' rule out values that are longer than allowed
Return False
End If
' search invalid chars
If Not System.Text.RegularExpressions.Regex.IsMatch(Value, _
"^[-A-Za-z0-9_@.]+$") Then Return False
' search the @ char
Dim i As Integer = Value.IndexOf("@"c)
' there must be at least three chars after the @
If i <= 0 Or i >= Value.Length - 3 Then Return False
' ensure there is only one @ char
If Value.IndexOf("@"c, i + 1) >= 0 Then Return False
' check that the domain portion contains at least one dot
Dim j As Integer = Value.LastIndexOf("."c)
' it can't be before or immediately after the @ char
If j < 0 Or j <= i + 1 Then Return False
' if we get here the address if validated
Return True
End Function
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